| TFYA47 |
Surfaces and interfaces, 6 ECTS credits.
/Ytor och gränsskikt /
For:
KeBi
MED
TB
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Prel. scheduled
hours: 54
Rec. self-study hours: 106
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Area of Education: Science
Main field of studies: Physics, Applied Physics, Engineering Biology
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Advancement level
(G1, G2, A): A
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Aim:
The course gives a general introduction to surfaces; their structure and physical-chemical properties, and interfaces between solids and organic materials or liquids. This includes hard surfaces (metals, dielectrics), soft matter surfaces (polymers and molecular films), free liquid surfaces and their interfaces, and colloidal systems. The course introduces analytical techniques for studies of surfaces, interfaces and thin films. After the course the student should be able to:
- Understand and describe properties of free liquid surfaces, such as surface tension, capillarity, wetting and spreading.
- Understand and describe electrical phenomena at surfaces, such as surface charge, surface potential, the electrical double layer, and basic electrochemical concepts.
- Describe the phase behaviour and aggregation of amphiphiles in solution and at interfaces.
- Desribe intermolecular forces, forces acting between molecules and surfaces, and surface forces.
- Describe common crystal structures of solid materials and understand the arrangement of atoms in surfaces made from such crystals.
- Describe the mechanisms that control the formation of overlayer structures on single crystal surfaces and classify such overlayer structures.
- Describe the shape and properties of common adsorption isoterms, and apply them for extraction of termodynamic or physicochemical data.
- Desribe the function and principles for common methods and instruments for surface and thin film analysis, as well as explain and interpret the information which can be obtained from these techniques.
- Desribe methods for the preparation and characterization of thin organic films on surfaces, in particular self-assembled monolayers.
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Prerequisites: (valid for students admitted to programmes within which the course is offered)
Basic knowledge of calculus in many variables, probability and statistics, classical physics, general chemistry, physical chemistry and quantum mechanics.
Note: Admission requirements for non-programme students usually also include admission requirements for the programme and threshhold requirements for progression within the programme, or corresponding.
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Supplementary courses:
Surface science, Biosensor technology, Microsystems and Nanobiology, Biomedical materials
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Organisation:
The material is presented in lectures, as well as classroom and laboratory exercises.
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Course contents:
Surface phases, surface energy, surface tension, surface excess. Free liquid surfaces, capillarity, Laplace' and Kelvin's equations. Wetting, contact angles, Young's equation. Surface charge, electrical double layer, Zeta potential. Amphiphilic aggregation and phase behaviour. Adsorption to liquid interfaces, Gibb's isotherm. Forces between molecules and between molecular systems and surfaces. Colloids and colloidal stability. The structure and properties of molecular films; preparation strategies, thermodynamically and kinetically controlled processes, surface modification, self-assembled monolayers.
Hard materials and surfaces, the structure of surfaces, the surface chemical bond, physisorption, chemisorption. Adsorption, adsorption kinetics and isotherms, surface reactions. Analytical methods for surface and interfacial analysis.
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Course literature:
Attard & Barnes, "Surfaces", Oxford University Press 1998.
Barnes & Gentle, "Interfacial science", 2nd ed, Oxford University Press 2011.
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Examination: |
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Written examination
Laboratory course
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4,5 ECTS
1,5 ECTS
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Course language is Swedish/English.
Department offering the course: IFM.
Director of Studies: Magnus Boman
Examiner: Thomas Ederth
Link to the course homepage at the department
Course Syllabus in Swedish
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